Modified MgH2 Hydrogen Storage Properties Based on Grapefruit Peel-Derived Biochar

نویسندگان

چکیده

Carbon materials play an important role in the development of solid hydrogen storage materials. The main purpose this work is to study low-cost synthesis biomass carbon (BC) and its positive effect on behavior magnesium hydride (MgH2). Herein, it proven that when used together with (MgH2), can be as adsorption desorption channel for hydrogen. initial dehydrogenation temperature MgH2 + 10 wt% BC composite 250 °C, which 110 °C lower than pure MgH2. In addition, system complete all processes within min at 350 °C. Meanwhile, 5.1 H2 also dehydrogenated 1 h 300 Under same conditions, hardly starts release After dehydrogenation, start absorb conditions 225 3 MPa, 6.13 absorbed h, basically reaching theoretical limit. Cycling experiments show has a good stability. cycles, capacity shows almost no obvious decline. It believed help research efficient carbon-based multifunctional catalysts.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Destabilized LiBH4/MgH2 for reversible hydrogen storage

DOE and FreedomCAR technical targets of 6.0 and 9.0 wt.% are set forth capacities to realize a “holy grail” for hydrogen storage systems for 2010 and 2015 respectively. Alkali metal complex hydrides with high theoretical hydrogen capacity, for example: LiBH4 (18 wt.%), are being investigated for their properties to store large quantities of hydrogen. The catalytic doping of SiO2, seems to enhan...

متن کامل

Impact of Stoichiometry on the Hydrogen Storage Properties of LiNH2-LiBH4-MgH2 Ternary Composites

We recently reported (Yang, J.; et al. Angew. Chem., Int. Ed. 2008, 47, 882) a novel hydrogen storage composite involving a 2:1:1 LiNH2:LiBH4:MgH2 ratio. On the basis of in-depth experimental and computational analysis, this composite was found to release hydrogen via a complex multistep reaction cascade, which seeded the products of a subsequent reversible hydrogen storage reaction. This so-ca...

متن کامل

Improved hydrogen storage properties of MgH2 doped with chlorides of transition metals Hf and Fe

The effects of HfCl4 and FeCl3 addition on the de/rehydrogenation properties of MgH2 were investigated. Both HfCl4 and FeCl3-doped MgH2 samples started to released hydrogen at about 270 °C, a decreased of about 70 °C and about 140 °C compared to as-milled and as-received MgH2, respectively. In terms of the desorption kinetics, the HfCl4-doped MgH2 sample showed significant improvement, with 6.0...

متن کامل

Remarkable hydrogen storage properties for nanocrystalline MgH2 synthesised by the hydrogenolysis of Grignard reagents.

The possibility of generating MgH(2) nanoparticles from Grignard reagents was investigated. To this aim, five Grignard compounds, i.e. di-n-butylmagnesium, tert-butylmagnesium chloride, allylmagnesium bromide, m-tolylmagnesium chloride, and methylmagnesium bromide were selected for the potential inductive effect of their hydrocarbon group in leading to various magnesium nanostructures at low te...

متن کامل

Enhanced hydrogen storage properties of MgH2 co-catalyzed with NbF5 and single-walled carbon nanotubes

The hydrogen storage performance of ball-milled MgH2 with 5 wt.% NbF5 + 5 wt.% single-walled carbon nanotubes as additives was investigated. We found that the hydrogen-sorption kinetics of magnesium is markedly improved by these co-additives. At 573 K, this hydride can absorb 6.3 wt.% hydrogen within 30 s. Even at 373 K, 5.2 wt.% of hydrogen can be absorbed within 10 min. This enhanced hydrogen...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Catalysts

سال: 2022

ISSN: ['2073-4344']

DOI: https://doi.org/10.3390/catal12050517